No they wouldn’t be able to destroy caps shield, they didn’t even destroy ultrons vibranium either. What happened was that ultrons inner body heated up and started to melt away, which meant his vibranium plating was falling off.
Comic ultron entire metal shell is adamantium, but the MCU version seems to only use a small armor of sorts. You can even see ultrons regular body under his vibranium one.
You can see in the images, that only his inner mechanics are melting red, while the vibranium is staying fine. You can even see pieces falling off.
vibranium is still very much indestructible. During when iron man and Thor blow up sokovia, the vibes of core stay completely intact. And both hit it with even more powerful attacks than what they used on ultron.
There’s only 2 examples of vibranium actually being broken.
first when wanda rips ultrons core from his body, and second when thanos breaks cap shield with his sword.
The thanos one is pretty easy to explain, he’s the strongest person in the galaxy, was pissed. Plus his sword is confirmed to have been made by Etri the dwarf from uru. (Same metal as Thor’s hammer).
stands to reason the only other metal capable of breaking vibranium would be a space mystic one.
when Wanda ripped ultrons core is also pretty explainable, her powers come from the infinity stones, (the most powerful objects in the universe). And her powers seem to fluctuate with her emotions. She noticeably gets stronger each movie, her bending vibranium as seen in the first image was cause of her brothers death, and emotional trauma.
Then we see her breaks thanos uru sword after her rage from his future self killing vision. The same sword that broke caps shield.
in conclusion vibranium is still the strongest metal on earth, barring other cosmic metals and abilities drived from cosmic objects Of power.....
Image source Google
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